Synthesis focused. Catalysis driven. At Max-Planck-Institut für Kohlenforschung
Mülheim an der Ruhr
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- Following 1,141
- Followers 13,134
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🚨Calling medicinal chemists🚨:
A Suzuki het-het coupling sometimes does not require complex ligands. An air stable Ni would do.
Amazing work from @rsaeb2 Rakan Saeb and Byeongdo Roh.
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Deciphering the mechanism of oxidative addition of aryl iodides into a red-light active bismuthinidene. Incredible team: Alexios Stamoulis,
@mato_mauro, Paolo Cleto-Bruzzese @MrIrieman, @GilSepulcre @CadraLab & Frank Neese. pubs.acs.org/doi/10.1021/jac…
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Transmetalating a challenging tetrel: introducing aryl-[Si] synthons into bismuth organometallic catalysis. Great work spearheaded by Teresa and Sophia. @angew_chem onlinelibrary.wiley.com/doi/…
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Expanding the horizons for bismuth as a redox catalyst. Now for cyclopropanation. @J_A_C_S pubs.acs.org/doi/epdf/10.102… with @ShengyangN & @DavideSpinnato2
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with @DavideSpinnato2, @Nils_Not_, @MrIrieman, M. van Gastel, L. Wagner and F. Neese
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Amination of heterocycles with naked nickel, now in @ChemRxiv by @rsaeb2 and Bryan B. chemrxiv.org/engage/chemrxiv…
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Congratulations Dr. Kuziola on passing your viva! @JenniferKuziola PhD #5! Enjoy your day!
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Yes, it is a bismuthinidene.
Yes, it is stable.
Yes, it is a triplet.
Yes, it is non-magnetic.
chemrxiv.org/engage/chemrxiv…
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Single electron oxidative addition at Bismuth unlocks radical cross-coupling catalysis in C-N couplings. Work led by @mato_mauro. Great job from all involved! chemrxiv.org/engage/chemrxiv…
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Activation of N-H and O-H bonds at Bi. Led by @sdyangxiu. A great story together with the @mpicec_press. Congrats to all people involved! @ChemRxiv chemrxiv.org/engage/chemrxiv…
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Aryl-S(VI)-Fluorides: strange compounds with rich chemistry. @M_Magre and @ShengyangN have organized the precedents and looked at their chemistry. Out now in @angew_chem . onlinelibrary.wiley.com/doi/… Congrats!
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Bismuth meets SuFEx: synthesis of (hetero)aryl sulfonyl fluorides through catalytic insertion of SO2 into Bi-C bonds. Reporting in @J_A_C_S the work of @M_Magre. pubs.acs.org/doi/10.1021/jac…
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Reporting in @J_A_C_S: low-valent Bi redox catalysis via elementary organometallic steps: catalytic hydrodefluorination. Excellent work by Yue (@YPYuePang) Markus (@MrIrieman), Nils and Felix! pubs.acs.org/doi/10.1021/jac…
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Bringing bismuth closer together. Great job @JenniferKuziola, @M_Magre and Nils!! @OrgBiomolChem pubs.rsc.org/en/Content/Arti…
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Another piece of the puzzle: Ni-norbornene as catalyst in low-temperature Kumada cross-coupling. Good job Sigrid, Lukas and Nils! @Orgmet_ACS pubs.acs.org/doi/10.1021/acs…
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Deaminative Chlorination of Aminoheterocycles: bringing the best of the Vilsmeier disconnection to late-stage. 5- and 6-member rings. >20 heterocyclic scaffolds. Sneak peak of what @ChemRxiv chemrxiv.org/articles/prepri… @ClementGhiazza, Teresa and Alejandro!
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Catalytic activation of N2O at a Bi-redox platform made possible by Yue. Together with @MrIrieman and Nils! @J_A_C_S pubs.acs.org/doi/10.1021/jac…
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@FranckF1476 revisited the C(sp3)-O-C(sp3) bond formation at high-valent Ni centers and found interesting structures and reactivity. A truly collaborative work at the Mülheim Chemistry Campus with @MrIrieman and Edward @mpicec_press! @J_A_C_S pubs.acs.org/doi/10.1021/jac…
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Access to an under-explored functional group: Ar-SOF3 onlinelibrary.wiley.com/doi/… @angew_chem
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Ni(4-tBustb)3: More stable. More robust. More nickel. @Orgmet_ACS @LNattmann pubs.acs.org/doi/10.1021/acs…
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Pyrylium tetrafluoroborate (Pyry-BF4) now available on @SigmaAldrich @MilliporeSigma. For examples of its power as NH2 activator: onlinelibrary.wiley.com/doi/…
onlinelibrary.wiley.com/doi/…
chemistry-europe.onlinelibra…
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Late but still valid: congratulations to Feng Wang for being named one of the finalist of the #ReaxysPhDPrize. Well done!!👍
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A new story on Bismuth Redox Catalysis: this time, triflate and nonaflate as nucleophiles. Great work from @uri_planas and Vytautas! pubs.acs.org/doi/pdf/10.1021…
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Our recent developments on pyrylium reagents:
- Pyry-BF4: Sulfonyl Fluoride Synthesis from Sulfonamides
onlinelibrary.wiley.com/doi/…
- ScPyry-OTf: Radical Borylation of Anilines
onlinelibrary.wiley.com/doi/…
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Ni(Fstb)3. An air-stable source of Ni(0). Thinking outside the (Glove)box. @LNattmann @rsaeb2 nature.com/articles/s41929-0…
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A radical alternative for the borylation of anilines. Now in @ChemRxiv chemrxiv.org/articles/Radica…
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Congratulations to our very own @FranckF1476 for winning the european championship of landsailing in Terschelling (NED)!! Amazing!!🥇🏆
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High-valent Bismuth Redox Catalysis unlocked. Now in @ChemRxiv: chemrxiv.org/articles/Cataly…
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Make sure to stop by at the posters from our laboratory at #omcos20 @OMCOSBoard!! Feng Wang will explain you all the adventures with Bi!👍🏽
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#fakenews we did not win the cup, but we stole it just for a quick picture! We will come back stronger next year for the KoFo Cup!! 💪🏾💪🏾 well done people!!!!! 5th place!!!
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Coming back to my office, after the department lecture at the MPI-Kofo. This group is da best!!👍🏽👍🏽💪🏾💪🏾
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The reductive Liebeskind-Srogl reaction developed by Yuanhong and Jose has been one of the most read articles in @J_A_C_S !! Congrats!! pubs.acs.org/doi/abs/10.1021…
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Thrilled to see our work with Pyry-BF4 highlighted in Synfacts! @thiemechemistry !! @DIYDuan @DMAO_92 👍🏽
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Lukas and Sigrid receiving the traditional beer shower to celebrate their great work being published in @J_A_C_S!! pubs.acs.org/doi/10.1021/jac…
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...and the countdown is over! Bringing catalysis to a forgotten beast. Congratulations to Lukas, Sigrid, Pascal and Richard!! pubs.acs.org/doi/10.1021/jac…
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Our paper on Pyry-BF4 reagent to functionalize Aminoheterocycles has been one of the most accessed of July in @angew_chem !! Congratulations Daniel, @DIYDuan, Yuanhong, Feng and Matt! onlinelibrary.wiley.com/page…
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Having trouble in retaining your C(sp3)-M in the cross-coupling of aryl electrophiles? here is an overview of methods available! @thiemechemistry thieme-connect.com/products/…
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Reading about Emergence, by Seth Herzon in Synlett @thiemechemistry thieme-connect.com/products/…
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Today we say goodbye to Yaya Duan 😢 The first postdoc in our group!! Best of luck in this new adventure at @ICIQchem in @MartinLab_ICIQ 👍🏽
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Beat the heat! beer pouring to beat the (unusual) 37 deg in Mülheim... Congrats Daniel and Yaya for the @angew_chem on the Pyry-BF4! onlinelibrary.wiley.com/doi/…
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Our postdoc Uri just got a Humboldt Fellowship!!! Congratulations, great achievement!! @AvHStiftung #celebration
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